Characterization of the Arene-Oxidizing Intermediate in ToMOH as a Diiron(III) Species
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چکیده
منابع مشابه
Characterization of the arene-oxidizing intermediate in ToMOH as a diiron(III) species.
We report the generation and characterization of a diiron(III) intermediate formed during reaction with dioxygen of the reduced hydroxylase component of toluene/o-xylene monooxygenase from Pseudomonas sp. OX1. The decay rate of this species is accelerated upon mixing with phenol, a substrate for this system. Under steady-state conditions, hydrogen peroxide was generated in the absence of substr...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2007
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja076121h